Product ID:142-0041 WHITE, SHER-MARK UPSIDE DOWN (SUPDAT)
MSDS Date:11/01/1995
FSC:8010
NIIN:00N062835
MSDS Number: CGZTM

SHERWIN-WILLIAMS CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760.

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 13%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

12.

CAS: 64742-89-8

Fraction By Weight: 7%

OSHA PEL N/K

ACGIH TLV: N/K

22.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

180.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 19%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM; 1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1); (CALCIUM CARBONATE)

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 22.9%

OSHA PEL N/K

ACGIH TLV: N/K

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 6-12%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

CARDIOVASCULAR SYSTEMS. RPTS HAVE ASSOC

RTECS: 9999999ZZ

CONTAINS A CHEM KNOWN TO STATE OF

RTECS: 9999999ZZ

KEEP AREA VENTD - DO

RTECS: 9999999ZZ

HEATERS - TURN OFF STOVES, ELEC TOOLS & APPLIANCES

RTECS: 9999999ZZ

APPRVD BONDING & GROUNDING PROCS. CONTENTS UNDER

RTECS: 9999999ZZ

120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT

RTECS: 9999999ZZ

DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF

RTECS: 9999999ZZ

PARTICULATES (LISTED "AS DUST" IN INGRED

RTECS: 9999999ZZ

SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC

RTECS: 9999999ZZ

TLV 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5

RTECS: 9999999ZZ

GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESS EXPOS TO VAPS/SPRAY MIS TS. REDNESS & ITCHING OR BURNING
SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOS. CHRONIC:
TOLUENE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: APPEARS ON THE NAVY LISTING OF
OCCUPATIONAL CHEMICAL REPRO HAZS. SEEK CONSULTATION FROM APPROP
HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE
HANDLING & EXPOS INFO . PR LNGD OVEREXP TO SOLVENT INGREDS LISTED
MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD FORMING, REPRO &
(ING 9)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM & QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP &
WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:
FLUSH EYE S W/LARGE AMOUNTS OF WATER FOR AT LEAST15 MINUTES. GET
MED ATTN. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.
DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MED
ATTN.

Flash Point:<0F,<-18C
Lower Limits:1.0%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP. WATER
SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT. APPLICATION TO HOT SURFS REQS SPEC PRECS. DURING EMER
CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMMABLE. KEEP
AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY
IGNITE EXPLO. DURING USE & UNTIL (ING 11)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY
MIST. AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. THESE
COATINGS MAY CNTN M ATLS CLASSIFIED AS NUISANCE (ING 16)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR PROPERLY FITTED, NIOSH APPRVD RESP ORG
VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR
DUST/MIST RESP APPRVD BY NIOS H FOR DUST WHICH MAY BE (ING 19)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC LIMS. REFER TO OSHA STDS 1910.94, 107, 108.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: MARKING PAINT. FIRE FIGHT PROC: TO PVNT PRESS
BUILD-UP & POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT.
EXPLO HAZ: HAZ. SYMPTOMS MAY NOT BE IMMED APPARENT. OBTAIN MED
ATTN.

Boiling Pt:B.P. Text:<325F,<163C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Volatile Org Content %:63
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>80

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
UNDER RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO
DETERM APPLIC EPA HAZ WASTE NUMBER. INCIN IN APPRVD FACILITY. DO
NOT INCIN CLSD CNTNR. DISP I/A/W FED, STATE & LOC REGS REGARDING
POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.